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Quantum field theory naturally began with the study of electromagnetic interactions, as the electromagnetic field was the only known classical field as of the 1920s.[8]: 1
Through the works of Born, Heisenberg, and Pascual Jordan in 1925–1926, a quantum theory of the free electromagnetic field (one with no interactions with matter) was developed via canonical quantization by treating the electromagnetic field as a set of quantum harmonic oscillators.[8]: 1 With the exclusion of interactions, however, such a theory was yet incapable of making quantitative predictions about the real world.[3]: 22
In his seminal 1927 paper The quantum theory of the emission and absorption of radiation, Dirac coined the term quantum electrodynamics (QED), a theory that adds upon the terms describing the free electromagnetic field an additional interaction term between electric current density and the electromagnetic vector potential. Using first-order perturbation theory, he successfully explained the phenomenon of spontaneous emission. According to the uncertainty principle in quantum mechanics, quantum harmonic oscillators cannot remain stationary, but they have a non-zero minimum energy and must always be oscillating, even in the lowest energy state (the ground state). Therefore, even in a perfect vacuum, there remains an oscillating electromagnetic field having zero-point energy. It is this quantum fluctuation of electromagnetic fields in the vacuum that "stimulates" the spontaneous emission of radiation by electrons in atoms. Dirac's theory was hugely successful in explaining both the emission and absorption of radiation by atoms; by applying second-order perturbation theory, it was able to account for the scattering of photons, resonance fluorescence and non-relativistic Compton scattering. Nonetheless, the application of higher-order perturbation theory was plagued with problematic infinities in calculations.[6]: 71
In 1928, Dirac wrote down a wave equation that described relativistic electrons: the Dirac equation. It had the following important consequences: the spin of an electron is 1/2; the electron g-factor is 2; it led to the correct Sommerfeld formula for the fine structure of the hydrogen atom; and it could be used to derive the Klein–Nishina formula for relativistic Compton scattering. Although the results were fruitful, the theory also apparently implied the existence of negative energy states, which would cause atoms to be unstable, since they could always decay to lower energy states by the emission of radiation.[6]: 71–72
The prevailing view at the time was that the world was composed of two very different ingredients: material particles (such as electrons) and quantum fields (such as photons). Material particles were considered to be eternal, with their physical state described by the probabilities of finding each particle in any given region of space or range of velocities. On the other hand, photons were considered merely the excited s
